3d and 4d coordination complexes and coordination polymers involving electroactive tetrathiafulvalene containing ligands
نویسندگان
چکیده
The “through bond” approach has been recently developed to increase the interaction between the mobile and localized d electrons in multifunctional molecular materials involving tetrathiafulvalene-based ligands. This paper reviews the 3d and 4d coordination complexes and polymers elaborated from a library of tetrathiafulvalene derivatives containing ligands obtained recently in our group. The different synthetic ways of the complexes are highlighted as well as their chemical and physical properties.
منابع مشابه
C(2)-symmetric chiral tetrathiafulvalene-bis(oxazolines) (TTF-BOX): new precursors for organic materials and electroactive metal complexes.
Chiral C(2)-symmetric electroactive bis(oxazolines) containing an EDT-TTF (ethylenedithio-tetrathiafulvalene) backbone, as promising multifunctional ligands and precursors for chiral molecular materials, were synthesized and structurally characterized, together with octahedral molybdenum and tungsten carbonyl complexes.
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